Publications

@article{nokey,

title = {Tunable Electrochemical Entropy through Solvent Ordering by a Supramolecular Host},

author = {Xia, K. T.; Rajan, A.; Surendranath, Y.; Bergman, R. G.; Raymond, K. N.; Toste, F. D.},

doi = {https://pubs.acs.org/doi/10.1021/jacs.3c10145},

year  = {2023},

date = {2023-11-13},

urldate = {2023-11-13},

journal = {J. Am. Chem. Soc.},

volume = {145},

issue = {46},

pages = {25463-25470},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Ouellette2021b,

title = {Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide β-diketiminate Halide and Pseudohalide Complexes},

author = {Erik T. Ouellette and Jorge Ivan Amaro Estrada and Daniel J. Lussier and Khetpakorn Chakarawet and Trevor D. Lohrey and Laurent Maron and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.organomet.1c00516},

issn = {1520-6041},

year  = {2022},

date = {2022-11-28},

journal = {Organometallics},

volume = {41},

number = {22},

pages = {3128--3137},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{nokey,

title = {Heterobimetallic-Mediated Dinitrogen Functionalization: N-C Bond Formation at Rhenium-Group 9 Diazenido Complexes},

author = {Ouellette, E.T.; Magdalenski, J.S.; Bergman, R.G.; Arnold, J. },

doi = {https://pubs.acs.org/doi/full/10.1021/acs.inorgchem.2c02463},

year  = {2022},

date = {2022-09-23},

urldate = {2022-09-23},

journal = {Inorg. Chem. },

volume = {61},

pages = {16064-16071},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{nokey,

title = {Engendering reactivity at group 5-heteroatom multiple bonds via π-loading},

author = {Fostvedt, J.I.; Mendoza, J.; Lopez-Flores, S.; Alcantar, D.; Bergman, R.G.; Arnold, J.},

doi = {https://pubs.rsc.org/en/content/articlelanding/2022/sc/d2sc02706b},

year  = {2022},

date = {2022-06-29},

urldate = {2022-06-29},

journal = {Chem. Sci. },

volume = {13},

pages = {8224-8242},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{nokey,

title = {Impact of Host Flexibility on Selectivity in a Supramolecular Host-Catalyzed Enantioselective aza-Darzens Reaction},

author = {Bierschenk, S.M.; Pan, J.Y.; Settineri, N.S. ; Warzok, U.; Bergman, R.G.; Raymond, K.N. ; Toste, F.D.},

doi = {https://pubs.acs.org/doi/10.1021/jacs.2c04182},

year  = {2022},

date = {2022-06-14},

urldate = {2022-06-14},

journal = {J. Am. Chem. Soc.},

volume = {144},

issue = {25},

pages = {11425-11433},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{nokey,

title = {Source of Rate Acceleration for Carbocation Cyclization in Biomimetic Supramolecular Cages},

author = {Nguyen, Q.N.; Xia, K.; Zhang, Y.; Chen, N.; Morimoto, M.; Pei, X.; Ha, Y.; Guo, J.; Yang, W.; Wang, L.P.; Bergman, R.G.; Raymond, K.N.; Toste, F. D.; Tantillo, D. },

doi = {https://pubs.acs.org/doi/full/10.1021/jacs.2c04179},

year  = {2022},

date = {2022-06-14},

urldate = {2022-06-14},

journal = {J. Am. Chem. Soc. },

volume = {144},

issue = {25},

pages = {11413-11424},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{nokey,

title = {“[3 + 2] Cycloadditions and Retrocycloadditions of Niobium Imido Complexes: An Experimental and Computational Mechanistic Study},

author = {Jain, A.; Fostvedt, J.I.; Kriegel, B.M.; Small, David W. ; Grant, L.N.; Bergman, R. G.; Arnold, J. },

doi = {https://doi.org/10.1021/acs.inorgchem.2c00428?urlappend=%3Fref%3DPDF&jav=VoR&rel=cite-as},

year  = {2022},

date = {2022-04-18},

urldate = {2022-04-18},

journal = {Inorg. Chem.},

volume = {61},

pages = {6574-6583},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Ouellette2022,

title = {Applications of Low-Valent Transition Metalates: Development of a Reactive Noncarbonyl Rhenium(I) Anion},

author = {Erik T. Ouellette and Julian S. Magdalenski and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.accounts.2c00013},

issn = {1520-4898},

year  = {2022},

date = {2022-03-01},

journal = {Acc. Chem. Res.},

volume = {55},

number = {5},

pages = {783--793},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Fostvedt2021,

title = {A Diverse Array of C–C Bonds Formed at a Tantalum Metal Center},

author = {Jade I. Fostvedt and Michael A. Boreen and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.inorgchem.1c01159},

issn = {1520-510X},

year  = {2021},

date = {2021-07-05},

journal = {Inorg. Chem.},

volume = {60},

number = {13},

pages = {9912--9931},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Ouellette2021,

title = {σ or π? Bonding interactions in a series of rhenium metallotetrylenes},

author = {Erik T. Ouellette and Ambre Carpentier and I. Joseph Brackbill and Trevor D. Lohrey and Iskander Douair and Laurent Maron and Robert G. Bergman and John Arnold},

doi = {10.1039/d1dt00129a},

issn = {1477-9234},

year  = {2021},

date = {2021-02-16},

journal = {Dalton Trans.},

volume = {50},

number = {6},

pages = {2083--2092},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Salt metathesis reactions between a low-valent rhenium(i) complex and a series of amidinate-supported tetrylenes led to rhenium metallotetrylenes with varying extents of Re–E multiple bonding.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Morimoto2021,

title = {Chemoselective and Site-Selective Reductions Catalyzed by a Supramolecular Host and a Pyridine–Borane Cofactor},

author = {Mariko Morimoto and Wendy Cao and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.0c12479},

issn = {1520-5126},

year  = {2021},

date = {2021-02-03},

journal = {J. Am. Chem. Soc.},

volume = {143},

number = {4},

pages = {2108--2114},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Sebastiani2020b,

title = {An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage},

author = {Federico Sebastiani and Trandon A. Bender and Simone Pezzotti and Wan-Lu Li and Gerhard Schwaab and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste and Teresa Head-Gordon and Martina Havenith},

doi = {10.1073/pnas.2012545117},

issn = {1091-6490},

year  = {2020},

date = {2020-12-29},

journal = {Proc. Natl. Acad. Sci. U.S.A.},

volume = {117},

number = {52},

pages = {32954--32961},

publisher = {Proceedings of the National Academy of Sciences},

abstract = {Significance

          Using a supramolecular assembly that catalyzes substrates in water, we show that the nanocage encapsulates a water cluster that is structurally and dynamically distinct from any known phase of water. It plays an important role in the driving force for guest encapsulation: The release of the highly unusual encapsulated water droplet creates a strong thermodynamic drive for the high-affinity binding of guests in aqueous solution for the supramolecular construct.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Sebastiani2020,

title = {An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage},

author = {Federico Sebastiani and Trandon A. Bender and Simone Pezzotti and Wan-Lu Li and Gerhard Schwaab and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste and Teresa Head-Gordon and Martina Havenith},

doi = {10.1073/pnas.2012545117},

issn = {1091-6490},

year  = {2020},

date = {2020-12-29},

journal = {Proc. Natl. Acad. Sci. U.S.A.},

volume = {117},

number = {52},

pages = {32954--32961},

publisher = {Proceedings of the National Academy of Sciences},

abstract = {Significance

          Using a supramolecular assembly that catalyzes substrates in water, we show that the nanocage encapsulates a water cluster that is structurally and dynamically distinct from any known phase of water. It plays an important role in the driving force for guest encapsulation: The release of the highly unusual encapsulated water droplet creates a strong thermodynamic drive for the high-affinity binding of guests in aqueous solution for the supramolecular construct.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Morimoto2020,

title = {Advances in supramolecular host-mediated reactivity},

author = {Mariko Morimoto and Stephen M. Bierschenk and Kay T. Xia and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1038/s41929-020-00528-3},

issn = {2520-1158},

year  = {2020},

date = {2020-12-00},

journal = {Nat Catal},

volume = {3},

number = {12},

pages = {969--984},

publisher = {Springer Science and Business Media LLC},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Miyamura2020,

title = {Heterogeneous Supramolecular Catalysis through Immobilization of Anionic M_{4}L_{6} Assemblies on Cationic Polymers},

author = {Hiroyuki Miyamura and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.0c09556},

issn = {1520-5126},

year  = {2020},

date = {2020-11-11},

journal = {J. Am. Chem. Soc.},

volume = {142},

number = {45},

pages = {19327--19338},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Fostvedt2020,

title = {1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes},

author = {Jade I. Fostvedt and Lauren N. Grant and Benjamin M. Kriegel and Andreas H. Obenhuber and Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1039/d0sc03489d},

issn = {2041-6539},

year  = {2020},

date = {2020-11-04},

journal = {Chem. Sci.},

volume = {11},

number = {42},

pages = {11613--11632},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Another slice of pi: the addition of a second π-donor ligand engenders 1,2-addition and [2 + 2] cycloaddition reactivity across Nb-imido and Nb-oxo bonds.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2020d,

title = {Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts},

author = {Trevor D. Lohrey and Guodong Rao and David W. Small and Erik T. Ouellette and Robert G. Bergman and R. David Britt and John Arnold},

doi = {10.1021/jacs.0c04719},

issn = {1520-5126},

year  = {2020},

date = {2020-08-12},

journal = {J. Am. Chem. Soc.},

volume = {142},

number = {32},

pages = {13805--13813},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2020c,

title = {Diverse Reactivity of a Rhenium(V) Oxo Imido Complex: [2 + 2] Cycloadditions, Chalcogen Metathesis, Oxygen Atom Transfer, and Protic and Hydridic 1,2-Additions},

author = {Trevor D. Lohrey and Emmanuel A. Cortes and Jade I. Fostvedt and Alexander K. Oanta and Anukta Jain and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.inorgchem.0c01589},

issn = {1520-510X},

year  = {2020},

date = {2020-08-03},

journal = {Inorg. Chem.},

volume = {59},

number = {15},

pages = {11096--11107},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2020b,

title = {Facile Activation of Triarylboranes by Rhenium(V) Oxo Imido Complexes},

author = {Trevor D. Lohrey and Emmanuel A. Cortes and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.inorgchem.0c00658},

issn = {1520-510X},

year  = {2020},

date = {2020-05-18},

journal = {Inorg. Chem.},

volume = {59},

number = {10},

pages = {7216--7226},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2020,

title = {Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates},

author = {Trevor D. Lohrey and Jade I. Fostvedt and Robert G. Bergman and John Arnold},

doi = {10.1039/c9cc09475j},

issn = {1364-548X},

year  = {2020},

date = {2020-03-31},

journal = {Chem. Commun.},

volume = {56},

number = {26},

pages = {3761--3764},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
We report a series of β-diketiminate (BDI) complexes in which tautomeric rhenium(iii) hydride and rhenium(i) protio-BDI species readily interconvert between the solid and solution states.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bergman2020,

title = {John E. Bercaw: A joint appreciation},

author = {Robert G. Bergman and Jay A. Labinger},

doi = {10.1016/j.poly.2019.114307},

issn = {0277-5387},

year  = {2020},

date = {2020-02-00},

journal = {Polyhedron},

volume = {177},

publisher = {Elsevier BV},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bergman2020b,

title = {Personal Statement for Eric Jacobsen Special Issue of ASC on the Occasion of his 60th Birthday},

author = {Robert G. Bergman},

doi = {10.1002/adsc.201900692},

issn = {1615-4169},

year  = {2020},

date = {2020-01-23},

journal = {Adv Synth Catal},

volume = {362},

number = {2},

pages = {279--280},

publisher = {Wiley},

abstract = {AbstractNo Abstractmagnified image

},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Huang2019,

title = {Enantioselective Kinetic Resolution/Desymmetrization of \textit{Para}‐Quinols: A Case Study in Boronic‐Acid‐Directed Phosphoric Acid Catalysis},

author = {Banruo Huang and Ying He and Mark D. Levin and Jaime A. S. Coelho and Robert G. Bergman and F. Dean Toste},

doi = {10.1002/adsc.201900816},

issn = {1615-4169},

year  = {2020},

date = {2020-01-23},

journal = {Adv Synth Catal},

volume = {362},

number = {2},

pages = {295--301},

publisher = {Wiley},

abstract = {AbstractA chiral phosphoric acid‐catalyzed kinetic resolution and desymmetrization of para‐quinols operating via oxa‐Michael addition was developed and subsequently subjected to mechanistic study. Good to excellent s‐factors/enantioselectivities were obtained over a broad range of substrates. Kinetic studies were performed, and DFT studies favor a hydrogen bonding activation mode. The mechanistic studies provide insights to previously reported chiral anion phase transfer reactions involving chiral phosphate catalysts in combination with boronic acids.magnified image

},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bierschenk2020,

title = {A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction},

author = {Stephen M. Bierschenk and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.9b13177},

issn = {1520-5126},

year  = {2020},

date = {2020-01-15},

journal = {J. Am. Chem. Soc.},

volume = {142},

number = {2},

pages = {733--737},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2019b,

title = {Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing},

author = {Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1039/c9dt04489b},

issn = {1477-9234},

year  = {2019},

date = {2019-12-10},

journal = {Dalton Trans.},

volume = {48},

number = {48},

pages = {17936--17944},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
The rhenium(i) salt Na[Re(η^{5}-Cp)(BDI)] can be cooled in solution under a dinitrogen atmosphere to selectively access complexes containing rhenium(iii) centers bound to direduced, doubly-bonded N_{2}(i.e.diazenide) fragments.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Fostvedt2019,

title = {Structural diversity in multinuclear tantalum polyhydrides formed \textit{via} reductive hydrogenolysis of metal–carbon bonds},

author = {Jade I. Fostvedt and Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1039/c9cc07686g},

issn = {1364-548X},

year  = {2019},

date = {2019-10-31},

journal = {Chem. Commun.},

volume = {55},

number = {88},

pages = {13263--13266},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Put the methyl to the metal: hydrogenolysis of metal–carbon bonds offers controlled access to low-valent early metal complexes.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2019,

title = {H_{2} Activation and Direct Access to Terminal Nitride and \textit{cyclo}-P_{3} Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate},

author = {Trevor D. Lohrey and Guodong Rao and R. David Britt and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.inorgchem.9b02556},

issn = {1520-510X},

year  = {2019},

date = {2019-10-07},

journal = {Inorg. Chem.},

volume = {58},

number = {19},

pages = {13492--13501},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bender2019b,

title = {A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length},

author = {Trandon A. Bender and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.9b05604},

issn = {1520-5126},

year  = {2019},

date = {2019-07-31},

journal = {J. Am. Chem. Soc.},

volume = {141},

number = {30},

pages = {11806--11810},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Baumgartner2019,

title = {The Quest for Double Vicinal C–H Bond Activation on the (η

          5:η

          5-Fulvalene)diiridium Platform: Syntheses and Structures of (η

          5:η

          5-Fulvalene)Ir2(ortho-μ-C6H4)(CO)2 (Ir–Ir) and Related Complexes},

author = {Judith Baumgartner and Robert Bergman and Bernd Kayser and Theodore Klupinski and Yong Park and K. Vollhardt and Michael West and Bolin Zhu},

doi = {10.1055/s-0037-1611736},

issn = {1437-210X},

year  = {2019},

date = {2019-06-00},

journal = {Synthesis},

volume = {51},

number = {11},

pages = {2409--2429},

publisher = {Georg Thieme Verlag KG},

abstract = {The fulvalene diiridium platform was scrutinized for its potential to effect double vicinal C–H activation of C6H6 and C6H12, respectively. For this purpose, an improved preparation of Fv[Ir(CO)2]2 was developed, and the syntheses of the new complexes FvIr(CO)2Ir(CO)(η

            2-C6F6), Fv[Ir(CO)(η

            2-C6F6)]2, Fv[Ir(CH2=CH2)2]2 (X-ray), Fv[Ir(PMe3)(H)2]2 (X-ray), and (2,2′,3,3′-tetra-tert-butylFv)[Ir(CO)2]2 were accomplished. When irradiated in C6H6, these molecules succeeded to varying degrees, and best for (2,2′,3,3′-tetra-tert-butylFv)[Ir(CO)2]2, in the double metalation of the aromatic ring to engender ligating Ir2(ortho-μ-C6H4)(CO)2 (Ir–Ir) moieties, in addition to their precursor mono(phenyliridium hydride) constructs. A competing photochemical pathway is evident by the formation of diastereomers of Fv (or 2,2’,3,3’-tetra-tert-butylFv) [Ir(CO)(Ph)(H)]2 and the resulting dehydrogenated ligated [Ir(CO)(Ph)]2 (Ir–Ir). The structures of FvIr2(ortho-µ-C6H4)(CO)2 (Ir–Ir) and trans-Fv[Ir(CO)(Ph)]2 (Ir–Ir) were corroborated by X-ray analyses. Efforts to realize C–H bond activations with C6H12 generally failed or fared very poorly, with the exception of the tert-butylFv system, which enabled single, but not further, insertion to give (2,2′,3,3′-tetra-tert-butylFv)[Ir(CO)(Cy)(H)][Ir(CO)2] in 34% yield. To explore the relevant chemistry of phenyl- and alkyliridium species attached to Fv, several such derivatives were made by independent routes, adding knowledge to the fundamental behavior of this category of molecules. Where appropriate and for comparative purposes, similar reactions were performed on the corresponding Cp- and 1,2-di-tert-butylCpIr(CO)2 relatives.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bender2019,

title = {Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics},

author = {Trandon A. Bender and Mariko Morimoto and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.8b11842},

issn = {1520-5126},

year  = {2019},

date = {2019-01-30},

journal = {J. Am. Chem. Soc.},

volume = {141},

number = {4},

pages = {1701--1706},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2018b,

title = {Heterotetrametallic Re–Zn–Zn–Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate},

author = {Trevor D. Lohrey and Laurent Maron and Robert G. Bergman and John Arnold},

doi = {10.1021/jacs.8b12494},

issn = {1520-5126},

year  = {2019},

date = {2019-01-16},

journal = {J. Am. Chem. Soc.},

volume = {141},

number = {2},

pages = {800--804},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2018,

title = {Reductions of a Rhenium(III) Terminal Oxo Complex by Isocyanides and Carbon Monoxide},

author = {Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.organomet.8b00238},

issn = {1520-6041},

year  = {2018},

date = {2018-10-22},

journal = {Organometallics},

volume = {37},

number = {20},

pages = {3552--3557},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hong2018b,

title = {Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts},

author = {Cynthia M. Hong and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/acs.accounts.8b00328},

issn = {1520-4898},

year  = {2018},

date = {2018-10-16},

journal = {Acc. Chem. Res.},

volume = {51},

number = {10},

pages = {2447--2455},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hong2018,

title = {Deconvoluting the Role of Charge in a Supramolecular Catalyst},

author = {Cynthia M. Hong and Mariko Morimoto and Eugene A. Kapustin and Nicola Alzakhem and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.8b01701},

issn = {1520-5126},

year  = {2018},

date = {2018-05-30},

journal = {J. Am. Chem. Soc.},

volume = {140},

number = {21},

pages = {6591--6595},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Ziegler2018,

title = {Hydroboration Reactivity of Niobium Bis(N-heterocyclic carbene)borate Complexes},

author = {Jessica A. Ziegler and Céline Prange and Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.inorgchem.8b00247},

issn = {1520-510X},

year  = {2018},

date = {2018-05-07},

journal = {Inorg. Chem.},

volume = {57},

number = {9},

pages = {5213--5224},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2017,

title = {Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand},

author = {Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1002/anie.201707957},

issn = {1521-3773},

year  = {2017},

date = {2017-11-06},

journal = {Angew Chem Int Ed},

volume = {56},

number = {45},

pages = {14241--14245},

publisher = {Wiley},

abstract = {AbstractThe reactivity of the oxo ReV β‐diketiminate, OReCl2(BDI), with various cyclopentadienide (Cp) sources has been investigated. As a result, we have developed a route to a new class of terminal oxo complexes of ReIII supported by olefin moieties of substituted cyclopentadienes. The success of this pathway is due to the electrophilic nature of the Cp ligand in the cation, [ORe(η5‐Cp)(BDI)]+ (3+), which allows for nucleophilic attack by a variety of reagents under mild conditions. In contrast, tBuNC was found to attack at the oxo moiety to produce isocyanate by oxygen atom transfer.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Kriegel2017b,

title = {Synthesis and Redox Chemistry of a Tantalum Alkylidene Complex Bearing a Metallaimidazole Ring},

author = {Benjamin M. Kriegel and Nikolas Kaltsoyannis and Ruchira Chatterjee and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.organomet.7b00448},

issn = {1520-6041},

year  = {2017},

date = {2017-09-25},

journal = {Organometallics},

volume = {36},

number = {18},

pages = {3520--3529},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Garner2017,

title = {Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination},

author = {Mary E. Garner and Bernard F. Parker and Stephan Hohloch and Robert G. Bergman and John Arnold},

doi = {10.1021/jacs.7b08323},

issn = {1520-5126},

year  = {2017},

date = {2017-09-20},

journal = {J. Am. Chem. Soc.},

volume = {139},

number = {37},

pages = {12935--12938},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hong2017,

title = {Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host},

author = {Cynthia M. Hong and David M. Kaphan and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.7b03812},

issn = {1520-5126},

year  = {2017},

date = {2017-06-14},

journal = {J. Am. Chem. Soc.},

volume = {139},

number = {23},

pages = {8013--8021},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bergman2017,

title = {Jerome A. Berson (1924\textbf{–}2017)},

author = {Robert G. Bergman},

doi = {10.1002/anie.201701770},

issn = {1521-3773},

year  = {2017},

date = {2017-04-10},

journal = {Angew Chem Int Ed},

volume = {56},

number = {16},

pages = {4385--4385},

publisher = {Wiley},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Kriegel2017,

title = {Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes},

author = {Benjamin M. Kriegel and Lara C. E. Naested and Grégory Nocton and K. V. Lakshmi and Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.inorgchem.6b02735},

issn = {1520-510X},

year  = {2017},

date = {2017-02-06},

journal = {Inorg. Chem.},

volume = {56},

number = {3},

pages = {1626--1637},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lohrey2016,

title = {Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex},

author = {Trevor D. Lohrey and Robert G. Bergman and John Arnold},

doi = {10.1021/acs.inorgchem.6b02122},

issn = {1520-510X},

year  = {2016},

date = {2016-11-21},

journal = {Inorg. Chem.},

volume = {55},

number = {22},

pages = {11993--12000},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Chen2016,

title = {New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks},

author = {Shuming Chen and Vlad Bacauanu and Tobias Knecht and Brandon Q. Mercado and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/jacs.6b08355},

issn = {1520-5126},

year  = {2016},

date = {2016-09-28},

journal = {J. Am. Chem. Soc.},

volume = {138},

number = {38},

pages = {12664--12670},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Liberman-Martin2016c,

title = {Functionalization of an iridium–diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources},

author = {Allegra L. Liberman-Martin and Micah S. Ziegler and Antonio G. DiPasquale and Robert G. Bergman and T. Don Tilley},

doi = {10.1016/j.poly.2016.03.044},

issn = {0277-5387},

year  = {2016},

date = {2016-09-00},

journal = {Polyhedron},

volume = {116},

pages = {111--115},

publisher = {Elsevier BV},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Levin2016,

title = {Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis},

author = {Mark D. Levin and David M. Kaphan and Cynthia M. Hong and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1021/jacs.6b05442},

issn = {1520-5126},

year  = {2016},

date = {2016-08-03},

journal = {J. Am. Chem. Soc.},

volume = {138},

number = {30},

pages = {9682--9693},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Liberman-Martin2016,

title = {Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism},

author = {Allegra L. Liberman-Martin and Daniel S. Levine and Wenjun Liu and Robert G. Bergman and T. Don Tilley},

doi = {10.1021/acs.organomet.5b01003},

issn = {1520-6041},

year  = {2016},

date = {2016-04-25},

journal = {Organometallics},

volume = {35},

number = {8},

pages = {1064--1069},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Wangweerawong2016,

title = {Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids},

author = {Apiwat Wangweerawong and Joshua R. Hummel and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/acs.joc.5b02700},

issn = {1520-6904},

year  = {2016},

date = {2016-02-19},

journal = {J. Org. Chem.},

volume = {81},

number = {4},

pages = {1547--1557},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Brown2016,

title = {Improved scope and diastereoselectivity of C–H activation in an expanded supramolecular host},

author = {Casey J. Brown and Akos Kokai and Gregory M. Miller and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1080/10610278.2015.1122196},

issn = {1029-0478},

year  = {2016},

date = {2016-02-01},

journal = {Supramolecular Chemistry},

volume = {28},

number = {1-2},

pages = {188--191},

publisher = {Informa UK Limited},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Kriegel2015,

title = {Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes},

author = {Benjamin M. Kriegel and Robert G. Bergman and John Arnold},

doi = {10.1021/jacs.5b11287},

issn = {1520-5126},

year  = {2016},

date = {2016-01-13},

journal = {J. Am. Chem. Soc.},

volume = {138},

number = {1},

pages = {52--55},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Ziegler2016,

title = {Unusual κ1 coordination of a β-diketiminate ligand in niobium complexes},

author = {Jessica A. Ziegler and Robert G. Bergman and John Arnold},

doi = {10.1039/c6dt02373h},

issn = {1477-9234},

year  = {2016},

date = {2016-00-00},

journal = {Dalton Trans.},

volume = {45},

number = {32},

pages = {12661--12668},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Incorporating the Cp ligand into a Nb-BDI-imido system results in a complex containing a κ^{1}-(N) bound BDI from which a chloride can be abstracted or substituted with a hydride to cause the return of the typical bidentate binding.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}