Publications

@article{Liberman-Martin2016b,

title = {Lewis acid–base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand},

author = {Allegra L. Liberman-Martin and Daniel S. Levine and Micah S. Ziegler and Robert G. Bergman and T. Don Tilley},

doi = {10.1039/c6cc02433e},

issn = {1364-548X},

year  = {2016},

date = {2016-00-00},

journal = {Chem. Commun.},

volume = {52},

number = {43},

pages = {7039--7042},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Z-type interactions between bis(perfluorophenyl)zinc and platinum(ii) diaryl complexes supported by 1,10-phenanthroline (phen), 2,2′-bipyridine (bpy), and bis(dimethylphosphino)ethane (dmpe) ligands are reported.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Ziegler2016,

title = {Unusual κ1 coordination of a β-diketiminate ligand in niobium complexes},

author = {Jessica A. Ziegler and Robert G. Bergman and John Arnold},

doi = {10.1039/c6dt02373h},

issn = {1477-9234},

year  = {2016},

date = {2016-00-00},

journal = {Dalton Trans.},

volume = {45},

number = {32},

pages = {12661--12668},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Incorporating the Cp ligand into a Nb-BDI-imido system results in a complex containing a κ^{1}-(N) bound BDI from which a chloride can be abstracted or substituted with a hydride to cause the return of the typical bidentate binding.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hart-Cooper2015b,

title = {Protein-like proton exchange in a synthetic host cavity},

author = {William M. Hart-Cooper and Carmelo Sgarlata and Charles L. Perrin and F. Dean Toste and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1073/pnas.1515639112},

issn = {1091-6490},

year  = {2015},

date = {2015-12-15},

journal = {Proc. Natl. Acad. Sci. U.S.A.},

volume = {112},

number = {50},

pages = {15303--15307},

publisher = {Proceedings of the National Academy of Sciences},

abstract = {Significance

          Water drives molecular interactions central to the chemistry of life. Critical to life’s metabolic machinery, enzymes catalyze reactions with remarkable selectivities and efficiencies resulting from noncovalent interactions between water, substrate, and the enzyme active site. Here, amide hydrogen–deuterium exchange kinetics provide quantification of the electronic and steric factors that influence exchange between water and a highly charged host molecule whose protective outer shell and hydrophobic cavity allow it to function like an enzyme. Investigations suggest that the host’s interior microenvironment reacts with encapsulated water in a manner that is correlated to the host’s ability to mediate acid catalysis, thereby providing a tool for developing enzyme-like microenvironments to mediate acid- or base catalysis.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Kaphan2015b,

title = {A supramolecular microenvironment strategy for transition metal catalysis},

author = {David M. Kaphan and Mark D. Levin and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1126/science.aad3087},

issn = {1095-9203},

year  = {2015},

date = {2015-12-04},

journal = {Science},

volume = {350},

number = {6265},

pages = {1235--1238},

publisher = {American Association for the Advancement of Science (AAAS)},

abstract = {Faster elimination inside a cavity

          

            Metals are adept at shuffling molecular bonds. They pry apart two atoms and then pair each one with a different partner. Sometimes the atoms get stuck on the metal, though, and the newly partnered products aren't released. Kaphan

            et al.

            designed a strategy for accelerating this elimination process (see the Perspective by Yan and Fujita). A hollow supramolecular capsule captured a gold or platinum complex and induced rapid bond formation between the carbon atoms in methyl groups bound to the metal. Generalization of this strategy could open the door to a wide range of chemical transformations that are currently held up by slow eliminations.

          

          

            Science

            , this issue p. 1235; see also p. 1165

          },

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Dalton2015,

title = {Supramolecular Ga_{4}L_{6}^{12–} Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer},

author = {Derek M. Dalton and Scott R. Ellis and Eva M. Nichols and Richard A. Mathies and F. Dean Toste and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1021/jacs.5b06317},

issn = {1520-5126},

year  = {2015},

date = {2015-08-19},

journal = {J. Am. Chem. Soc.},

volume = {137},

number = {32},

pages = {10128--10131},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Kaphan2015,

title = {Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization},

author = {David M. Kaphan and F. Dean Toste and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1021/jacs.5b01261},

issn = {1520-5126},

year  = {2015},

date = {2015-07-29},

journal = {J. Am. Chem. Soc.},

volume = {137},

number = {29},

pages = {9202--9205},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Chen2015b,

title = {Regio- and Diastereoselective Synthesis of Highly Substituted, Oxygenated Piperidines from Tetrahydropyridines},

author = {Shuming Chen and Brandon Q. Mercado and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/acs.joc.5b00816},

issn = {1520-6904},

year  = {2015},

date = {2015-07-02},

journal = {J. Org. Chem.},

volume = {80},

number = {13},

pages = {6660--6668},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Chen2015,

title = {Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines},

author = {Shuming Chen and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/acs.orglett.5b00979},

issn = {1523-7052},

year  = {2015},

date = {2015-06-05},

journal = {Org. Lett.},

volume = {17},

number = {11},

pages = {2567--2569},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Brown2015,

title = {Supramolecular Catalysis in Metal–Ligand Cluster Hosts},

author = {Casey J. Brown and F. Dean Toste and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1021/cr4001226},

issn = {1520-6890},

year  = {2015},

date = {2015-05-13},

journal = {Chem. Rev.},

volume = {115},

number = {9},

pages = {3012--3035},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Liberman-Martin2015,

title = {Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound},

author = {Allegra L. Liberman-Martin and Robert G. Bergman and T. Don Tilley},

doi = {10.1021/jacs.5b02807},

issn = {1520-5126},

year  = {2015},

date = {2015-04-29},

journal = {J. Am. Chem. Soc.},

volume = {137},

number = {16},

pages = {5328--5331},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Zhang2015,

title = {Mechanism and Catalytic Impact of Ir–Ta Heterobimetallic and Ir–P Transition Metal/Main Group Interactions on Alkene Hydrogenation},

author = {Ying Zhang and Samuel P. Roberts and Robert G. Bergman and Daniel H. Ess},

doi = {10.1021/cs501884j},

issn = {2155-5435},

year  = {2015},

date = {2015-03-06},

journal = {ACS Catal.},

volume = {5},

number = {3},

pages = {1840--1849},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Tobisch2015,

title = {Aluminium-catalysed intramolecular hydroamination of aminoalkenes: computational perusal of alternative pathways for aminoalkene activation},

author = {Sven Tobisch},

doi = {10.1039/c5dt00121h},

issn = {1477-9234},

year  = {2015},

date = {2015-00-00},

journal = {Dalton Trans.},

volume = {44},

number = {27},

pages = {12169--12179},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Rival mechanistic pathways for CC bond activation in aluminium-catalysed hydroamination: computational mechanistic analysis reveals that a catalytically relevant [(pda)Al(NHR)] compound promotes hydroamination through a stepwise σ-bond insertive mechanism with turnover-limiting aminolysis.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hart-Cooper2015,

title = {The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations},

author = {William M. Hart-Cooper and Chen Zhao and Rebecca M. Triano and Parastou Yaghoubi and Haxel Lionel Ozores and Kristen N. Burford and F. Dean Toste and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1039/c4sc02735c},

issn = {2041-6539},

year  = {2015},

date = {2015-00-00},

journal = {Chem. Sci.},

volume = {6},

number = {2},

pages = {1383--1393},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
Catalyst and substrate modification, product selectivity and kinetic studies comprehensively describe a new class of terpenoid cyclase mimics.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Gianetti2015,

title = {Electron localization in a mixed-valence diniobium benzene complex},

author = {Thomas L. Gianetti and Grégory Nocton and Stefan G. Minasian and Nikolas Kaltsoyannis and A. L. David Kilcoyne and Stosh A. Kozimor and David K. Shuh and Tolek Tyliszczak and Robert G. Bergman and John Arnold},

doi = {10.1039/c4sc02705a},

issn = {2041-6539},

year  = {2015},

date = {2015-00-00},

journal = {Chem. Sci.},

volume = {6},

number = {2},

pages = {993--1003},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
One electron oxidation of a neutral diniobium benzene complex leads to a mixed-valence species. Single crystal X-ray diffraction, EPR, L_{3,2}-edge XANES, and DFT indicate that the unpaired electron is localized on one metal center.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Nechayev2015,

title = {C–F sp^{2} bond functionalization mediated by niobium complexes},

author = {Michael Nechayev and Thomas L. Gianetti and Robert G. Bergman and John Arnold},

doi = {10.1039/c5dt02082d},

issn = {1477-9234},

year  = {2015},

date = {2015-00-00},

journal = {Dalton Trans.},

volume = {44},

number = {45},

pages = {19494--19500},

publisher = {Royal Society of Chemistry (RSC)},

abstract = {
The functionalization of fluorobenzene is described via insertion of isocyanide after the oxidative addition of the C–F bond.
},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Camp2014,

title = {Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of \textit{cyclo}-P_{4} Inverted Sandwich Compounds},

author = {Clément Camp and Laurent Maron and Robert G. Bergman and John Arnold},

doi = {10.1021/ja5107282},

issn = {1520-5126},

year  = {2014},

date = {2014-12-17},

journal = {J. Am. Chem. Soc.},

volume = {136},

number = {50},

pages = {17652--17661},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Zhao2014,

title = {Nucleophilic Substitution Catalyzed by a Supramolecular Cavity Proceeds with Retention of Absolute Stereochemistry},

author = {Chen Zhao and F. Dean Toste and Kenneth N. Raymond and Robert G. Bergman},

doi = {10.1021/ja508799p},

issn = {1520-5126},

year  = {2014},

date = {2014-10-15},

journal = {J. Am. Chem. Soc.},

volume = {136},

number = {41},

pages = {14409--14412},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Johnson2014,

title = {Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors},

author = {Miles W. Johnson and Antonio G. DiPasquale and Robert G. Bergman and F. Dean Toste},

doi = {10.1021/om500663m},

issn = {1520-6041},

year  = {2014},

date = {2014-08-25},

journal = {Organometallics},

volume = {33},

number = {16},

pages = {4169--4172},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Wangweerawong2014,

title = {Asymmetric Synthesis of α-Branched Amines via Rh(III)-Catalyzed C–H Bond Functionalization},

author = {Apiwat Wangweerawong and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ja5033452},

issn = {1520-5126},

year  = {2014},

date = {2014-06-18},

journal = {J. Am. Chem. Soc.},

volume = {136},

number = {24},

pages = {8520--8523},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hastings2014,

title = {Origins of Large Rate Enhancements in the Nazarov Cyclization Catalyzed by Supramolecular Encapsulation},

author = {Courtney J. Hastings and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1002/chem.201303885},

issn = {1521-3765},

year  = {2014},

date = {2014-04-00},

journal = {Chemistry A European J},

volume = {20},

number = {14},

pages = {3966--3973},

publisher = {Wiley},

abstract = {AbstractThe self‐assembled supramolecular host [Ga4L6]12− (1; L=N,N‐bis(2,3‐dihydroxybenzoyl)‐1,5‐diaminonaphthalene) catalyzes the Nazarov cyclization of 1,3‐pentadienols with extremely high levels of efficiency. The catalyzed reaction proceeds at a rate over a million times faster than that of the background reaction, an increase comparable to those observed in some enzymatic systems. A detailed study was conducted to elucidate the reaction mechanism of both the catalyzed and uncatalyzed Nazarov cyclization of pentadienols. Kinetic analysis and 18O‐exchange experiments implicate a mechanism, in which encapsulation, protonation, and water loss from substrate are reversible, followed by irreversible electrocyclization. Although electrocyclization is rate determining in the uncatalyzed reaction, the barrier for water loss and for electrocyclization are nearly equal in the assembly‐catalyzed reaction. Analysis of the energetics of the catalyzed and uncatalyzed reaction revealed that transition‐state stabilization contributes significantly to the dramatically enhanced rate of the catalyzed reaction.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Obenhuber2014,

title = {Reaction of (Bisimido)niobium(V) Complexes with Organic Azides: [3 + 2] Cycloaddition and Reversible Cleavage of β-Diketiminato Ligands Involving Nitrene Transfer},

author = {Andreas H. Obenhuber and Thomas L. Gianetti and Xavier Berrebi and Robert G. Bergman and John Arnold},

doi = {10.1021/ja413194z},

issn = {1520-5126},

year  = {2014},

date = {2014-02-26},

journal = {J. Am. Chem. Soc.},

volume = {136},

number = {8},

pages = {2994--2997},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Zhao2013b,

title = {Ligand-Based Carbon–Nitrogen Bond Forming Reactions of Metal Dinitrosyl Complexes with Alkenes and Their Application to C–H Bond Functionalization},

author = {Chen Zhao and Mark R. Crimmin and F. Dean Toste and Robert G. Bergman},

doi = {10.1021/ar400176x},

issn = {1520-4898},

year  = {2014},

date = {2014-02-18},

journal = {Acc. Chem. Res.},

volume = {47},

number = {2},

pages = {517--529},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Gianetti2014,

title = {Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorination},

author = {Thomas L. Gianetti and Robert G. Bergman and John Arnold},

doi = {10.1039/c4sc00006d},

issn = {2041-6539},

year  = {2014},

date = {2014-00-00},

journal = {Chem. Sci.},

volume = {5},

number = {6},

publisher = {Royal Society of Chemistry (RSC)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Kriegel2014,

title = {Generation of low-valent tantalum species by reversible C–H activation in a cyclometallated tantalum hydride complex},

author = {Benjamin M. Kriegel and Robert G. Bergman and John Arnold},

doi = {10.1039/c4dt00923a},

issn = {1477-9234},

year  = {2014},

date = {2014-00-00},

journal = {Dalton Trans.},

volume = {43},

number = {26},

publisher = {Royal Society of Chemistry (RSC)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Zhao2013,

title = {Chiral Amide Directed Assembly of a Diastereo- and Enantiopure Supramolecular Host and its Application to Enantioselective Catalysis of Neutral Substrates},

author = {Chen Zhao and Qing-Fu Sun and William M. Hart-Cooper and Antonio G. DiPasquale and F. Dean Toste and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1021/ja411631v},

issn = {1520-5126},

year  = {2013},

date = {2013-12-18},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {50},

pages = {18802--18805},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bowring2013,

title = {Isolation of a Dicationic Platinum Complex with Two Accessible Coordination Sites},

author = {Miriam A. Bowring and Robert G. Bergman and T. Don Tilley},

doi = {10.1021/om4008357},

issn = {1520-6041},

year  = {2013},

date = {2013-10-14},

journal = {Organometallics},

volume = {32},

number = {19},

pages = {5266--5268},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{LaPierre2013,

title = {Vanadium Bisimide Bonding Investigated by X-ray Crystallography,^{51}V and^{13}C Nuclear Magnetic Resonance Spectroscopy, and V L_{3,2}-Edge X-ray Absorption Near-Edge Structure Spectroscopy},

author = {Henry S. La Pierre and Stefan G. Minasian and Mark Abubekerov and Stosh A. Kozimor and David K. Shuh and Tolek Tyliszczak and John Arnold and Robert G. Bergman and F. Dean Toste},

doi = {10.1021/ic4020543},

issn = {1520-510X},

year  = {2013},

date = {2013-10-07},

journal = {Inorg. Chem.},

volume = {52},

number = {19},

pages = {11650--11660},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Bowring2013b,

title = {Pt-Catalyzed C–C Activation Induced by C–H Activation},

author = {Miriam A. Bowring and Robert G. Bergman and T. Don Tilley},

doi = {10.1021/ja406260j},

issn = {1520-5126},

year  = {2013},

date = {2013-09-04},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {35},

pages = {13121--13128},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lian2013b,

title = {Facile Synthesis of Unsymmetrical Acridines and Phenazines by a Rh(III)-Catalyzed Amination/Cyclization/Aromatization Cascade},

author = {Yajing Lian and Joshua R. Hummel and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ja406131a},

issn = {1520-5126},

year  = {2013},

date = {2013-08-28},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {34},

pages = {12548--12551},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Liberman-Martin2013,

title = {A Remote Lewis Acid Trigger Dramatically Accelerates Biaryl Reductive Elimination from a Platinum Complex},

author = {Allegra L. Liberman-Martin and Robert G. Bergman and T. Don Tilley},

doi = {10.1021/ja404339u},

issn = {1520-5126},

year  = {2013},

date = {2013-07-03},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {26},

pages = {9612--9615},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Gianetti2013b,

title = {Dis-assembly of a Benzylic CF_{3} Group Mediated by a Niobium(III) Imido Complex},

author = {Thomas L. Gianetti and Robert G. Bergman and John Arnold},

doi = {10.1021/ja4033007},

issn = {1520-5126},

year  = {2013},

date = {2013-06-05},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {22},

pages = {8145--8148},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lian2013,

title = {Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture},

author = {Yajing Lian and Robert G. Bergman and Luke D. Lavis and Jonathan A. Ellman},

doi = {10.1021/ja402761p},

issn = {1520-5126},

year  = {2013},

date = {2013-05-15},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {19},

pages = {7122--7125},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Brasse2013,

title = {Mechanistic Study of the Oxidative Coupling of Styrene with 2-Phenylpyridine Derivatives Catalyzed by Cationic Rhodium(III) via C–H Activation},

author = {Mikaël Brasse and Juan Cámpora and Jonathan A. Ellman and Robert G. Bergman},

doi = {10.1021/ja401561q},

issn = {1520-5126},

year  = {2013},

date = {2013-05-01},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {17},

pages = {6427--6430},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Mugridge2013,

title = {Solvent and Pressure Effects on the Motions of Encapsulated Guests: Tuning the Flexibility of a Supramolecular Host},

author = {Jeffrey S. Mugridge and Achim Zahl and Rudi van Eldik and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1021/ja309949q},

issn = {1520-5126},

year  = {2013},

date = {2013-03-20},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {11},

pages = {4299--4306},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Gianetti2013,

title = {Diniobium Inverted Sandwich Complexes with μ-η^{6}:η^{6}-Arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure},

author = {Thomas L. Gianetti and Grégory Nocton and Stefan G. Minasian and Neil C. Tomson and A. L. David Kilcoyne and Stosh A. Kozimor and David K. Shuh and Tolek Tyliszczak and Robert G. Bergman and John Arnold},

doi = {10.1021/ja311966h},

issn = {1520-5126},

year  = {2013},

date = {2013-02-27},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {8},

pages = {3224--3236},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Ischay2013,

title = {Unstabilized Azomethine Ylides for the Stereoselective Synthesis of Substituted Piperidines, Tropanes, and Azabicyclo[3.1.0] Systems},

author = {Michael A. Ischay and Michael K. Takase and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ja312311k},

issn = {1520-5126},

year  = {2013},

date = {2013-02-20},

journal = {J. Am. Chem. Soc.},

volume = {135},

number = {7},

pages = {2478--2481},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Duttwyler2013,

title = {Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis},

author = {Simon Duttwyler and Shuming Chen and Michael K. Takase and Kenneth B. Wiberg and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1126/science.1230704},

issn = {1095-9203},

year  = {2013},

date = {2013-02-08},

journal = {Science},

volume = {339},

number = {6120},

pages = {678--682},

publisher = {American Association for the Advancement of Science (AAAS)},

abstract = {Acid-Derived Diversity

          

            Compounds with nitrogen-bearing rings have proven rather promising in pharmaceutical research, spurring the need for improved synthetic methods to access structurally diverse variants of this motif.

            

              Duttwyler

              et al.

            

            (p.

            678

            ) show that applying acids of different strengths to a dihydropyridine intermediate leads to selective protonation at either of two sites, depending on whether the reaction proceeds under kinetic or thermodynamic (that is, equilibrated) control. The protonations in turn activate the rings for addition of various carbon nucleophiles to the periphery, thereby affording multiple different substitution patterns for use in screening studies.

          },

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Martin2013,

title = {Synthesis of Isoquinuclidines from Highly Substituted Dihydropyridines via the Diels–Alder Reaction},

author = {Rhia M. Martin and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ol303040r},

issn = {1523-7052},

year  = {2013},

date = {2013-02-01},

journal = {Org. Lett.},

volume = {15},

number = {3},

pages = {444--447},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Wang2013,

title = {A supramolecular approach to combining enzymatic and transition metal catalysis},

author = {Z. Jane Wang and Kristen N. Clary and Robert G. Bergman and Kenneth N. Raymond and F. Dean Toste},

doi = {10.1038/nchem.1531},

issn = {1755-4349},

year  = {2013},

date = {2013-02-00},

journal = {Nature Chem},

volume = {5},

number = {2},

pages = {100--103},

publisher = {Springer Science and Business Media LLC},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Lian2012,

title = {Rhodium(III)‐Catalyzed Alkenyl CH Bond Functionalization: Convergent Synthesis of Furans and Pyrroles},

author = {Yajing Lian and Tatjana Huber and Kevin D. Hesp and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1002/anie.201207995},

issn = {1521-3773},

year  = {2013},

date = {2013-01-07},

journal = {Angew Chem Int Ed},

volume = {52},

number = {2},

pages = {629--633},

publisher = {Wiley},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Johnson2013,

title = {Preparation and reactivity of terminal gold(i) amides and phosphides},

author = {Miles W. Johnson and Sophia L. Shevick and F. Dean Toste and Robert G. Bergman},

doi = {10.1039/c2sc21519e},

issn = {2041-6539},

year  = {2013},

date = {2013-00-00},

journal = {Chem. Sci.},

volume = {4},

number = {3},

pages = {1023--1027},

publisher = {Royal Society of Chemistry (RSC)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{LaPierre2012,

title = {Carbon Monoxide, Isocyanide, and Nitrile Complexes of Cationic, d^{0} Vanadium Bisimides: π-Back Bonding Derived from the π Symmetry, Bonding Metal Bisimido Ligand Orbitals},

author = {Henry S. La Pierre and John Arnold and Robert G. Bergman and F. Dean Toste},

doi = {10.1021/ic302044q},

issn = {1520-510X},

year  = {2012},

date = {2012-12-17},

journal = {Inorg. Chem.},

volume = {51},

number = {24},

pages = {13334--13344},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hart-Cooper2012,

title = {Selective Monoterpene-like Cyclization Reactions Achieved by Water Exclusion from Reactive Intermediates in a Supramolecular Catalyst},

author = {William M. Hart-Cooper and Kristen N. Clary and F. Dean Toste and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1021/ja308254k},

issn = {1520-5126},

year  = {2012},

date = {2012-10-31},

journal = {J. Am. Chem. Soc.},

volume = {134},

number = {43},

pages = {17873--17876},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Colby2011,

title = {Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions},

author = {Denise A. Colby and Andy S. Tsai and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ar200190g},

issn = {1520-4898},

year  = {2012},

date = {2012-06-19},

journal = {Acc. Chem. Res.},

volume = {45},

number = {6},

pages = {814--825},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Hesp2012,

title = {Rhodium-Catalyzed Synthesis of Branched Amines by Direct Addition of Benzamides to Imines},

author = {Kevin D. Hesp and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ol300723x},

issn = {1523-7052},

year  = {2012},

date = {2012-05-04},

journal = {Org. Lett.},

volume = {14},

number = {9},

pages = {2304--2307},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Koller2011b,

title = {Controlled Hydrosilylation of Carbonyls and Imines Catalyzed by a Cationic Aluminum Alkyl Complex},

author = {Jürgen Koller and Robert G. Bergman},

doi = {10.1021/om2008277},

issn = {1520-6041},

year  = {2012},

date = {2012-04-09},

journal = {Organometallics},

volume = {31},

number = {7},

pages = {2530--2533},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Duttwyler2012,

title = {Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade},

author = {Simon Duttwyler and Colin Lu and Arnold L. Rheingold and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ja2119833},

issn = {1520-5126},

year  = {2012},

date = {2012-03-07},

journal = {J. Am. Chem. Soc.},

volume = {134},

number = {9},

pages = {4064--4067},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Martin2012,

title = {Synthesis of Pyridines from Ketoximes and Terminal Alkynes via C–H Bond Functionalization},

author = {Rhia M. Martin and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/jo202280e},

issn = {1520-6904},

year  = {2012},

date = {2012-03-02},

journal = {J. Org. Chem.},

volume = {77},

number = {5},

pages = {2501--2507},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Mugridge2012,

title = {Equilibrium Isotope Effects on Noncovalent Interactions in a Supramolecular Host–Guest System},

author = {Jeffrey S. Mugridge and Robert G. Bergman and Kenneth N. Raymond},

doi = {10.1021/ja2067324},

issn = {1520-5126},

year  = {2012},

date = {2012-02-01},

journal = {J. Am. Chem. Soc.},

volume = {134},

number = {4},

pages = {2057--2066},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Tauchert2012,

title = {Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate},

author = {Michael E. Tauchert and Christopher D. Incarvito and Arnold L. Rheingold and Robert G. Bergman and Jonathan A. Ellman},

doi = {10.1021/ja211110h},

issn = {1520-5126},

year  = {2012},

date = {2012-01-25},

journal = {J. Am. Chem. Soc.},

volume = {134},

number = {3},

pages = {1482--1485},

publisher = {American Chemical Society (ACS)},

keywords = {},

pubstate = {published},

tppubtype = {article}

}